4-({[(E)-Pyridin-3-ylmethylidene]amino}methyl)cyclohexanecarboxylic acid
نویسندگان
چکیده
The title compound, C(14)H(18)N(2)O(2), contains two geometrically different mol-ecules in the asymmetric unit: the basal plane of the cyclo-hexane chair and the N-[pyridin-3-yl-methyl-idene]methanamine moiety are oriented at dihedral angles of 71.77 (7)° and 83.42 (8)°. In the crystal, the mol-ecules are linked by O-H⋯N hydrogen bonds, generating C(13) head-to-tail chains extending along the base vector [103]. R(2) (2)(26) ring motifs are formed due to the C-H⋯·O inter-actions that link neighbouring chains. There also exist π-π inter-actions [centroid-centroid separation = 3.6925 (12) Å] between the symmetry-related pyridine rings of one of the independent mol-ecules.
منابع مشابه
(E)-4-{[(Pyridin-4-ylmethylidene)amino]methyl}benzoic acid
The title mol-ecule, C(14)H(12)N(2)O(2), exhibits a V-shaped conformation with a dihedral angle of 59.69 (3)° between the benzene and pyridine rings. In the crystal, O-H⋯N hydrogen bonds link the mol-ecules into zigzag chains along [010].
متن کاملPoly[[[μ3-(E)-N-(pyridin-4-ylmethylidene)hydroxylaminato-κ3 O:N:N′][μ2-(E)-N-(pyridin-4-ylmethylidene)hydroxylamine-κ2 N:N′][(E)-N-(pyridin-4-ylmethylidene-κN)hydroxylamine]disilver(I)] nitrate]
The title coordination polymer, {[Ag2(C6H5N2O)(C6H6N2O)2]NO3} n , features a deprotonated N-(pyridin-4-yl-methyl-idene)hy-droxy-laminate anion and two neutral N-(pyridin-4-yl-methyl-idene)hydroxyl-amine mol-ecules in the asymmetric unit. The anion connects three Ag(I) atoms through its O and two N-donor atoms. One neutral ligand functions in a monodentate mode; the other functions in a bridging...
متن کامل[(E)-Oxido(pyridin-2-ylmethylidene)amine-κ2 N,N′][(E)-N-(pyridin-2-ylmethylidene)hydroxylamine-κ2 N,N′]silver(I) perchlorate–bis[(E)-N-(pyridin-2-ylmethylidene)hydroxylamine-κ2 N,N′]silver(I) (1/1)
In the title salt co-crystal, [Ag(C(6)H(5)N(2)O)(C(6)H(6)N(2)O)]ClO(4)·[Ag(C(6)H(6)N(2)O)(2)], the asymmetric unit comprises a [Ag(LH)(2)](+) cation, a perchlorate anion and a neutral (LH)AgL mol-ecule, where LH is pyridine-2-carboxaldoxime. Both silver-containing species feature N,N'-chelating LH and L ligands, which define an N(4) donor set that is highly distorted [dihedral angles between Ag...
متن کاملBenzoic acid–4-{(1E)-[(E)-2-(pyridin-4-ylmethylidene)hydrazin-1-ylidene]methyl}pyridine (2/1)
In the title co-crystal, C(12)H(10)N(4)·2C(7)H(6)O(2), the complete 4-pyridine-aldazine mol-ecule is generated by a crystallographic centre of inversion. In the crystal, mol-ecules are connected into a three component aggregate via O-H⋯N hydrogen bonds. As both the benzoic acid [O-C-C-C torsion angle = 174.8 (2)°] and 4-pyridine-aldazine (r.m.s. deviation of the 16 non-H atoms = 0.041 Å) mol-ec...
متن کاملBis[N-(2-hydroxyethyl)-N-propyldithiocarbamato-κ2 S,S′]bis(4-{[(pyridin-4-ylmethylidene)hydrazinylidene]methyl}pyridine-κN 1)cadmium
The complete mol-ecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octa-hedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S'-chelating dithio-carbamate anions and two pyridine N atoms derived from two monodentate 4-pyridine-aldazine (or 4-{[(pyridin-4-yl-methyl-idene)hyd...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011